Braided Core Structure Boosts Energy Density in Fiber Lithium-Ion Batteries
An ultrathin braided wire in the core of an electrode increases the
energy density of lithium-ion batteries, a team of researchers reports
in the journal Angewandte Chemie. Batteries of this kind could be
incorporated into functional textiles and used to supply power to
smartphones and other electronic devices while we are wearing them. The
new braided current collector structure replaces a single continuous
wire and improves ion transport within the electrode, increasing charge
density.
© Wiley-VCH, re-use with credit to 'Angewandte Chemie' and a link to the original article.
Lithium-ion batteries (LIBs) are ubiquitous in devices ranging from
smartphones to electric cars. We know them as made of a stack of
electrodes in a bulky or cylindrical design. A novel battery variant
reduces the stack to the dimensions of a thread made up of two long
electrode fibers wound around each other. Woven into fabric, these very
lightweight fiber batteries (FLIBs) can supply power to wearable
electronics. Fiber batteries were declared one of IUPAC’s Top Ten
Emerging Technologies in Chemistry in 2022.
However, there is a problem which needs to be solved before fiber
batteries can be used to supply power to tents, functional clothing, and
more; particularly in long fibers, energy density is far too low to be
useful. Huisheng Peng and a team of researchers at the Fudan University
in Shanghai (China) have now discovered that redesigning the current
collector of the electrode could solve this problem.
The team decided to replace the current collector, which is a
continuous, thin metal wire inside the graphite electrode, with a braid
made of several much thinner metal threads. To produce the braid, they
unwound several ultra-thin metal threads from spindles and braided them
into a central braided thread, which was then coated with graphite over
the whole electrode.
The new braided current collector was just as stable as the
continuous wire, but made it possible to increase the energy density by
interacting with the graphite. As the team explain: “The designed
braiding structure leads to channels filled with active materials,
reducing obstruction to lithium ion transport and increasing loading
capability of active materials." This increased energy density was also
demonstrated in tests: a woven textile was produced, containing 40
one-meter-long FLIBs with braided current collectors. This FLIB-based
textile was able to charge a smartphone from 30 to 57 percent, whereas
the conventional FLIB design using a continuous current collector wire
only managed to reach 52 percent.
This increase in efficiency was achieved by a relatively simple
change in the design of the current collector. This is particularly
important for long fiber batteries which have to be robust, stable and
also light.
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About the Author
Huisheng Peng is a Professor at the
Department of Macromolecular Science, Jiangwan Campus of Fudan
University, Shanghai, China. The research interests of his team focus on
functional composite materials, energy harvesting and storage materials
and devices, energy medicine, and fiber electronics.
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